Barcelona drew Paris Saint-Germain in the round of 16 of the 20-21 Champions League.
The two clubs last met in 2017 when Barcelona defeated PSG 6-1 in the second leg to recover from a 4-0 first leg defeat.
Neymar subsequently left Barcelona for PSG that summer and this will be his first return.
Borussia Monchengladbach vs. Manchester City
Lazio vs. Bayern Munich
Atletico Madrid vs. Chelsea
RB Leipzig vs. Liverpool
Porto vs. Juventus
Barcelona vs. Paris Saint-Germain
Sevilla vs. Borussia Dortmund
Atalanta vs. Real Madrid